One of the problems with paper recycling is that the fibers stiffen during the dewatering and drying processes, also known as hornification. The same thing happens to, for example, dishcloths, which stiffen over time. New research can now explain the mechanisms of hornification, knowledge that will enable us to recycle paper fibers many more times compared to today, which is five to seven times.
- Through our studies, we now know at what level of dryness the hornification process begins, already at a dry content of 20 percent, says Björn Sjöstrand, Docent in Chemical Engineering. We also know at what temperatures hornification begins, already at temperatures as low as 40° C, but the biggest changes are seen at temperatures above 100° C. The solvent also plays a role, if we replace the water in the paper pulp with other solvents, it reduces the hornification. This implies that the hydrogen bonds that form in the water environment contribute to the hornification of the fibers.
Ekmandagarna 2024
The research findings were presented during Ekmandagarna 2024, an annual conference organised by the Swedish Association of Pulp and Paper Engineers (SPCI). The findings can also be found in several newly published scientific papers.
- It was a great honour to have the opportunity to present our results at this year’s Ekmandagarna, which brings together many participants from across the paper industry, both academics and industry representatives. Our hope is that this research can contribute to improved paper recycling where the fibers can be recycled many more times, says Björn Sjöstrand. In addition, this new knowledge of the hornification process can lead to reduced use of raw materials in paper manufacturing, as it allows for closer control of the durability properties of paper materials.
Increased circularity
Greater insight into the process of hornification has many advantages. The research can hopefully contribute to new dewatering processes for the industry, which in turn will create more recycling opportunities and improved product properties. Hopes are that it will be possible to circulate the fiber up to 25 times, compared to five to seven times today. The most important areas where knowledge of hornification can be applied are market pulp, dry broke, recycling, dissolving pulp and mirco- and nanocellulose applications.
Sustainable use of resources
The research provides new insights into hornification, a research area with the potential of providing more opportunities for the forest industry to understand the changes in the binding capacity of wood fibres during the dewatering process. Hornification is when chemical bonds occur inside the fibers. This prevents the fibers from swelling and reduces their flexibility and external fibrils. Flexible fibres and external fibrils are important for developing strength properties when manufacturing cardboard and paper.
- By using fewer fibres but still retaining the same level of mechanical performance in the products, you get a more optimised utilisation of the raw materials, says Björn Sjöstrand. This means that the results of our project will contribute to both increased recycling and more sustainable use of resources.
Research for a circular bioeconomy
The research is part of the research environment Pro2BE, Processes and Products for a Circular Bioeconomy, at Karlstad University. Pro2BE is focused on research and education related to conversion to a bioeconomy based on sustainable and eco-friendly renewable resources. Another focus area is the development of the forest industry.
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